A 32-year-old woman was robbed at gunpoint and hit by the suspects' getaway car late Saturday night in Newburgh.
Police say it happened behind the back entrance to the state Thruway rest stop.
Two men, 36-year-old Adam Colandrea and 24-year-old Steven Wolfe, are facing robbery charges.
Wolfe was also charged with escape. He allegedly shoved an officer and made a run for it out the police station door, before being taken back into custody.
Police say a gun that they recovered was stolen.
The woman was not seriously hurt during the incident.